(51)
Int.Cl.4
H
01 J 61/20
H
01 J 61/40
(19) Federal Republic of Germany
[emblem]
German Patent Office
(12)
Offenlegungsschrift
[=
Published Patent Application]
(11)
DE 38 13 421 A1
(21) Application
number: P 38 13 421.7
(22) Filing date: April 21, 1988
(43) Disclosure
date: November 2, 1989
|
(71) Applicant: Philips Patentverwaltung GmbH,
2000 Hamburg, DE |
(72) Inventors: Fischer, Ernst, Dr., 5190
Stolberg, DE, Hörster, Horst, Dr., 5106
Roetgen, DE |
(54) High Pressure Mercury Vapor Discharge Lamp
High
pressure mercury vapor discharge lamp with an envelope (2) containing two
tungsten electrodes (9, 10) and a filling, which, in addition to rare gas,
contains an amount of mercury that exceeds 0.2 mg/mm3 at a mercury
vapor pressure exceeding 200 bar, and at least one of the halogens - chlorine,
bromine, or iodine - in an amount ranging from 10-6 to 10-4
mmol/mm3. The wall load during operation is
higher than 1 W/mm2.
[see
figure]
DE 3813421
A1
German
Federal Printing Office 09.89 908
844/285 6/60
Specification
The
invention relates to a high pressure mercury vapor discharge lamp with an
envelope, which is made of a material that is stable to high temperature. Said
envelope contains two tungsten electrodes and a filling, which comprises in
essence mercury, a rare gas and halogen, which is free in the operating state.
In operation the wall load of the envelope is higher than 1 W/mm2.
The envelope, which is stable to high temperature, may be made, for example, of
quartz glass or aluminum oxide.
This
type of super high pressure mercury vapor discharge lamp, which is known from
the DE-AS 14 89 417 has an elongated quartz glass envelope having a volume of
55 mm3. This envelope is filled with rare gas and 6.5 mg of mercury;
this is equivalent to a quantity of mercury of 0.12 mg/mm3. The
mercury vapor pressure may be about 120 bar. The lamp has a wall load of about
14.5 W/mm3. In order to increase the lifespan, not only the wall of
the envelope is cooled, for example, by means of flowing water, but also 5 x 10-4
to 5 x 10-2 g. atoms of at least one of the halogens per cubic
millimeter are fed into the envelope.
Although such lamps at mercury vapor
pressures of more than 100 bar produce a high luminance and a relatively
continuous spectrum, they yield essentially a typical mercury spectrum with a
low content of red.
The GB
PS 11 09 135 discloses a super high pressure mercury vapor discharge lamp
comprising a capillary tube, which is made of quartz glass and which is filled
with mercury up to a quantity of 0.15 mg per cubic millimeter of volume; this
is equivalent to a mercury vapor pressure of about 150 bar. In order to improve
the color rendering, this lamp is, moreover, filled with at least one metal
iodide. The high electrode load of these lamps results in the evaporation of
the tungsten from the electrodes and the deposition of said tungsten on the
wall of the envelope. This leads to a blackening of the envelope, as a result
of which the latter is heated to an extremely high temperature, which in turn
may give rise to an explosion of the envelope, especially at high mercury vapor
pressures.
Therefore, the object of the invention
is to provide a high pressure mercury vapor discharge lamp, which has not only
a high luminance but also a good color rendering and a long lifespan.
This
object is achieved in a high pressure mercury vapor discharge lamp of the kind
mentioned in the introductory part in that the quantity of mercury is larger
than 0.2 mg/mm3 and that the mercury vapor pressure during operation
is higher than 200 bar and that at least one of the halogens - chlorine,
bromine, or iodine - is present in a quantity between 10-6 and 10-4
mmol/mm3.
Up to a
mercury vapor pressure of about 150 bar, the light output and the color
rendering properties of mercury high pressure lamps are practically constant
because in essence a line radiation of the mercury is emitted and an amount of
continuous radiation, which originates from the recombination of electrons and
mercury atoms. It was a surprise to find that at higher mercury vapor pressures
there is a significant increase in the light output and the color rendering
index. This increase is due to a drastic increase in the amount of continuous
radiation. It is presumed that at high pressures of more than 200 bar, not only
a continuous emission from quasi molecular states but also the band emission of
real, bonded molecular states also make a significant contribution. At an
operating pressure of about 300 bar, the continuum part of the visible
radiation lies well above 50%. As a result, the red content of the emitted
light spectrum is also increased.
In order
to maintain this high mercury vapor pressure, the wall temperature of the
envelope has to be high (about 1,000 deg. C). Moreover, the lamp envelope has
to withstand this high pressure. Therefore, the envelop has to be kept as small
as possible.
The
upper limit of the mercury vapor pressure depends upon the strength of the
material of the envelope, but in practical cases may be about 400 bar.
Preferably the quantity of mercury ranges from 0.2 to 0.35 mg/mm3;
and the mercury vapor pressure ranges from 200 to 350 bar.
The very
small dimensions of the envelope could lead to an increased blackening of the
wall by the tungsten that has evaporated from the electrodes. However, such a
blackening of the wall must be absolutely avoided, because otherwise the wall
temperature increases during the lifetime due to increased absorption of
thermal radiation, which in turn would lead to the destruction of the envelope
of the lamp. As a measure to avoid such a blackening of the wall by the
tungsten transport, the high pressure mercury vapor discharge lamp of the
invention contains a small quantity of at least one of the halogens - chlorine,
bromine or iodine. These halogens bring about a tungsten transport cycle, by
means of which the tungsten, which is deposited on the envelope of the lamp, is
transported back to the electrodes.
It is
efficacious for the high pressure discharge lamp of the invention to use as the
halogen bromine, which is introduced into the lamp in the form of CH2Br2
at a filling pressure of about 0.1 mbar.
The
mercury vapor discharge lamp, according to the invention, does not contain a
metal halide, because such a high metal halide concentration would be required
for a substantial increase of the continuum part of the radiation that a very
rapid corrosion of the electrodes would occur as a consequence of the high
tungsten transport rates. Therefore, heavily loaded metal halide lamps, as
described, for example, in the GB‑PS 11 09 135, typically reach only
lifespans of a few hundred hours, whereas in the lamps, according to the
invention, lifespans of more than 5,000 hours could be reached with a
substantially constant light output (Dh
< 2%) and substantially constant color rendering properties (Dx, Dy < 0.005 during 5,000 hours). In this case h stands for the efficiency; and x and y stand for the
color coordinates.
The
lamps, according to the invention, have a color temperature of more than 8,000
K. The drawback with this high color temperature and the color rendering, which
is worse as compared to metal halogenide lamps, can be improved in a discharge
lamp according to the invention in that the lamp is surrounded by a filter to
block blue radiation content.
In this
context it should be pointed out that it is known from the GB‑PS 15 39
429 to reduce the blue content of the radiation in high pressure mercury vapor
discharge lamps with the addition of halide by the use of a filter and, thus,
to achieve an improvement in the color of the emitted radiation. In mercury
vapor discharge lamps at a mercury vapor pressure of up to about 150 bar, such
a filter would be practically ineffective, because the emitted light exhibits
almost no red content. However, the spectrum of the inventive lamp contains
such a high content of the continuous red radiation that with the use of a
filter for the blue radiation content, with a loss of light of only 15%, it is
possible to achieve an emission of white light having a color temperature of
5,500 K and a color rendering index of 70.
At this
point a few embodiments of the invention are described with reference to the
drawings. In the drawing:
Figure 1 depicts
a high pressure mercury vapor discharge lamp having an elliptical lamp
envelope.
Figure 2 depicts
a high pressure mercury vapor discharge lamp having a cylindrical lamp envelope
that is surrounded by an outer envelope, which is coated with a filter.
Figure 3 depicts
the emitted light spectrum of a high pressure mercury vapor discharge lamp at a
mercury vapor pressure of more than 200 bar; and
Figure 4 depicts
the transmission spectrum of a filter that is used in the lamp, shown in Figure
2.
The high
pressure mercury vapor discharge lamp 1, depicted in Figure 1, has an
elliptical lamp envelope 2 that is made of quartz glass. The envelope ends are
adjoined by cylindrical quartz parts 3 and 4, into which molybdenum foils 5 and
6 are molten in a vacuum tight manner. The inner ends of the molybdenum foils 5
and 6 are connected to the pole leads 7 and 8, which carry the electrodes 9 and
10 that are made of tungsten.
The
outer ends of the molybdenum foils 5 and 6 are adjoined by current supply wires
11 and 12 that are made of molybdenum and that run to the exterior.
The high
pressure mercury vapor discharge lamp 13, depicted in Figure 2, is constructed
in a manner similar to the lamp, depicted in Figure 1. However, the envelope 14
of the lamp exhibits a cylindrical shape. The lamp 13 is surrounded by an outer
envelope 15, which is made of quartz glass and which is coated on the inner
side with an interference filter 16. This filter 16 serves to reduce the blue
radiation that is emitted by the lamp 13.
Below are
the data of a few practical embodiments:
Lamp
1
Elliptical
lamp envelope, according to Figure 1, having a wall thickness of 1.8 mm. The
inside dimensions and operating data are:
length 7 mm
diameter 2.5
mm
envelope
volume 23 mm3
electrode
gap 1.2 mm
filling:
mercury 5 mg Hg (0.218 mg/mm3)
halogen 5 x 10-6 mmol/mm3
CH2Br2
operating
pressure approximately 170 bar
power 50 W
operating
voltage 70 V
light
output 56
lm/W
wall
load 1.30 W/mm2
Lamp 2
Elliptical lamp envelope, according to Figure 1, having a
wall thickness of 1.7 mm. The inside dimensions and operating data are:
length 5 mm
diameter 2.5 mm
envelope
volume 16.5 mm3
electrode
gap 1.0 mm
filling:
mercury 4 mg Hg (0.243 mg/mm3)
halogen 5 x 10-6 mmol/mm3
CH2Br2
operating
pressure approximately 220 bar
power 40 W
operating
voltage 80 V
light
output 56
lm/W
wall
load 1.30 W/mm2
Lamp 3
Cylindrical lamp envelope, according to Figure 2, having
a wall thickness of 1.3 mm without an outer envelop. The inside dimensions and
operating data are:
length 4 mm
diameter 1.5
mm
envelope
volume 7 mm3
electrode
gap 1.0 mm
filling:
mercury 2.5 mg Hg (0.357 mg/mm3)
halogen 5 x 10-6 mmol/mm3
CH2Br2
operating
pressure 300 bar
power 30 W
operating
voltage 92 V
light
output 60
lm/W
wall
load 1.36 W/mm2
The
described lamps have a color temperature of more than 8,000 K; however, the
color rendering is significantly improved in comparison with lamps having a low
operating pressure. For example, the color rendering index Ra is for
the three lamps, just described, 51.5, 55.2 and 61.6, whereas with a lamp,
corresponding to example 1, at an operating pressure of 100 bar only a color
rendering index of 32.7 was attained.
In
Figure 3, the light spectrum that is emitted by a lamp, according to Example 2,
is plotted as the intensity I over the wavelength l. It shows that the continuum portion of the visible
radiation is about 50%.
In the
lamp, according to Figure 2, the interference filter 16 consists, for example,
of an alternating sequence of layers of chemically modified titanium dioxide
and amorphous silicon dioxide. Such interference filters are the subject mater
of the German patent application P 37 24 216.4. In a practical embodiment, the
filter that is used had a degree of transmission Tr, as shown in Figure 4, as a
function of the wavelength l. The results are reflected in the following lighting
technical data:
Without
a filter:
color temperature: 8,580 K
color
rendering index: 55.2
light
output: 56 lm/W
With a
filter:
color
temperature: 5,500 K
color
rendering index: 69.7
light
output: 48 lm/W
This
shows that the interference filter causes not only a significant reduction in
the color temperature, but also at the same time a significant improvement in
the color rendering index.
Although
in comparison with comparable, heavily loaded metal halide lamps, the inventive
lamps exhibit a somewhat lower light output and, moreover, during operation
without a filter also exhibit poorer color rendering properties, the inventive
lamps exhibit an extremely high constancy of the lighting technical data, a
light output that does not change during the service life, and a very long
life. While lifespans of a few hundred hours are attained with heavily loaded
metal halide lamps, the inventive lamps do not exhibit any changes even after a
service life of more than 5,000 hours.
Patent
Claims
1. High pressure mercury vapor discharge lamp with an
envelope, which is made of a material that is stable to high temperature and
which contains two tungsten electrodes and a filling, which comprises in
essence mercury, rare gas, and halogen, which is free in the operating state,
and the load on the envelope wall during operation is higher than 1 W/mm2,
characterized in that the amount of mercury exceeds 0.2 mg/mm3 and
the mercury vapor pressure exceeds 200 bar and that at least one of the
halogens - chlorine, bromine, or iodine - is present in an amount ranging from
10-6 to 10-4 mmol/mm3.
2. Discharge lamp, as claimed in claim 1, characterized
in that the quantity of mercury ranges from 0.2 to 0.35 mg/mm3; and
the mercury vapor pressure during operation ranges from 200 to 350 bar.
3. Discharge lamp, as claimed in any one of the preceding
claims, characterized in that the lamp is surrounded by a filter for the blue
radiation content.